<?xml version="1.0" encoding="UTF-8"?>
<!--

       Copyright 2011 Peter Murray-Rust et. al.

       Licensed under the Apache License, Version 2.0 (the "License");
       you may not use this file except in compliance with the License.
       You may obtain a copy of the License at

           http://www.apache.org/licenses/LICENSE-2.0

       Unless required by applicable law or agreed to in writing, software
       distributed under the License is distributed on an "AS IS" BASIS,
       WITHOUT WARRANTIES OR CONDITIONS OF ANY KIND, either express or implied.
       See the License for the specific language governing permissions and
       limitations under the License.

-->

<fragment  convention="cml:PML-explicit" xmlns:g="http://www.xml-cml.org/mols/geom1" xmlns="http://www.xml-cml.org/schema">
  <!-- nylon3 alternative repeat-->
  <molecule role="fragment" id="nsp2_1">
    <atomArray>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="6.874474431786602" y3="7.364333152820824" z3="1.6836317786234933" id="nsp2_1_r1">
        <label dictRef="cml:torsionEnd">r2</label>
        <label dictRef="cml:torsionEnd">r3</label>
      </atom>
      <atom elementType="N" x3="7.470354790502688" y3="7.21912165" z3="2.1153032017509776" formalCharge="0" hydrogenCount="0" id="nsp2_1_n1"/>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.566039463978429" y3="6.583384494925069" z3="2.5015449821412834" id="nsp2_1_r3"> </atom>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.942576318205662" y3="7.801681433336589" z3="2.103860841299773" id="nsp2_1_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
    </atomArray>
    <bondArray>
      <bond order="S" id="nsp2_1_r1_nsp2_1_n1" atomRefs2="nsp2_1_r1 nsp2_1_n1"/>
      <bond order="S" id="nsp2_1_n1_nsp2_1_r2" atomRefs2="nsp2_1_n1 nsp2_1_r2"/>
      <bond order="S" id="nsp2_1_n1_nsp2_1_r3" atomRefs2="nsp2_1_n1 nsp2_1_r3"/>
    </bondArray>
    <join atomRefs2="g:nsp2_1_r3 g:h_2_r1" moleculeRefs2="g:nsp2_1 g:h_2" order="S">
      <molecule role="fragment" id="h_2">
        <atomArray>
          <atom elementType="H" x3="1.998" y3="-0.064" z3="-0.0" formalCharge="0" hydrogenCount="0" id="h_2_a1"/>
          <atom title="H" elementType="R" formalCharge="0" hydrogenCount="0" x3="1.6979020929575936" y3="0.15242838582026894" z3="0.0" id="h_2_r1"/>
        </atomArray>
        <bondArray>
          <bond order="S" id="h_2_a1_h_2_r1" atomRefs2="h_2_a1 h_2_r1"/>
        </bondArray>
      </molecule>
    </join>
  </molecule>
  <join atomRefs2="g:nsp2_1_r2 g:carbonyl_3_r1" moleculeRefs2="g:nsp2_1 g:carbonyl_3" order="S">
    <torsion>180</torsion>
  </join>
  <molecule role="fragment" id="carbonyl_3">
    <atomArray>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="6.858584288887507" y3="7.368205459562712" z3="1.672120540673427" id="carbonyl_3_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="7.470354790502688" y3="7.21912165" z3="2.1153032017509776" formalCharge="0" hydrogenCount="0" id="carbonyl_3_c1"/>
      <atom elementType="O" x3="7.621770771606594" y3="6.2131009200000005" z3="2.7265105769419966" formalCharge="0" hydrogenCount="0" id="carbonyl_3_o2"> </atom>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.955168892277741" y3="7.817216360892232" z3="2.1035557116877412" id="carbonyl_3_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
    </atomArray>
    <bondArray>
      <bond order="S" id="carbonyl_3_r1_carbonyl_3_c1" atomRefs2="carbonyl_3_r1 carbonyl_3_c1"/>
      <bond order="D" id="carbonyl_3_c1_carbonyl_3_o2" atomRefs2="carbonyl_3_c1 carbonyl_3_o2"/>
      <bond order="S" id="carbonyl_3_c1_carbonyl_3_r2" atomRefs2="carbonyl_3_c1 carbonyl_3_r2"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:carbonyl_3_r2 g:ch2_4_r1" moleculeRefs2="g:carbonyl_3 g:ch2_4" order="S"/>
  <molecule role="fragment" id="ch2_4">
    <atomArray>
      <atom elementType="R" x3="1.0927029508094934" y3="0.019313350096244575" z3="-0.04489307394726355" id="ch2_4_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="0.703" y3="-0.593" z3="-0.302" id="ch2_4_a2"/>
      <atom elementType="R" x3="-0.00448114334248928" y3="-0.593" z3="0.0019250430859626966" id="ch2_4_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
      <atom elementType="H" x3="0.631" y3="-0.548" z3="-1.389" id="ch2_4_a6"/>
      <atom elementType="H" x3="1.224" y3="-1.505" z3="-0.01" id="ch2_4_a7"/>
    </atomArray>
    <bondArray>
      <bond order="1" id="ch2_4_r1_ch2_4_a2" atomRefs2="ch2_4_r1 ch2_4_a2"/>
      <bond order="1" id="ch2_4_a2_ch2_4_r2" atomRefs2="ch2_4_a2 ch2_4_r2"/>
      <bond order="1" id="ch2_4_a2_ch2_4_a6" atomRefs2="ch2_4_a2 ch2_4_a6"/>
      <bond order="1" id="ch2_4_a2_ch2_4_a7" atomRefs2="ch2_4_a2 ch2_4_a7"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:ch2_4_r2 g:ch2_5_r1" moleculeRefs2="g:ch2_4 g:ch2_5" order="S"/>
  <molecule role="fragment" id="ch2_5">
    <atomArray>
      <atom elementType="R" x3="1.0927029508094934" y3="0.019313350096244575" z3="-0.04489307394726355" id="ch2_5_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="0.703" y3="-0.593" z3="-0.302" id="ch2_5_a2"/>
      <atom elementType="R" x3="-0.00448114334248928" y3="-0.593" z3="0.0019250430859626966" id="ch2_5_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
      <atom elementType="H" x3="0.631" y3="-0.548" z3="-1.389" id="ch2_5_a6"/>
      <atom elementType="H" x3="1.224" y3="-1.505" z3="-0.01" id="ch2_5_a7"/>
    </atomArray>
    <bondArray>
      <bond order="1" id="ch2_5_r1_ch2_5_a2" atomRefs2="ch2_5_r1 ch2_5_a2"/>
      <bond order="1" id="ch2_5_a2_ch2_5_r2" atomRefs2="ch2_5_a2 ch2_5_r2"/>
      <bond order="1" id="ch2_5_a2_ch2_5_a6" atomRefs2="ch2_5_a2 ch2_5_a6"/>
      <bond order="1" id="ch2_5_a2_ch2_5_a7" atomRefs2="ch2_5_a2 ch2_5_a7"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:ch2_5_r2 g:nsp2_6_r1" moleculeRefs2="g:ch2_5 g:nsp2_6" order="S"/>
  <molecule role="fragment" id="nsp2_6">
    <atomArray>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="6.874474431786602" y3="7.364333152820824" z3="1.6836317786234933" id="nsp2_6_r1">
        <label dictRef="cml:torsionEnd">r2</label>
        <label dictRef="cml:torsionEnd">r3</label>
      </atom>
      <atom elementType="N" x3="7.470354790502688" y3="7.21912165" z3="2.1153032017509776" formalCharge="0" hydrogenCount="0" id="nsp2_6_n1"/>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.566039463978429" y3="6.583384494925069" z3="2.5015449821412834" id="nsp2_6_r3"> </atom>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.942576318205662" y3="7.801681433336589" z3="2.103860841299773" id="nsp2_6_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
    </atomArray>
    <bondArray>
      <bond order="S" id="nsp2_6_r1_nsp2_6_n1" atomRefs2="nsp2_6_r1 nsp2_6_n1"/>
      <bond order="S" id="nsp2_6_n1_nsp2_6_r2" atomRefs2="nsp2_6_n1 nsp2_6_r2"/>
      <bond order="S" id="nsp2_6_n1_nsp2_6_r3" atomRefs2="nsp2_6_n1 nsp2_6_r3"/>
    </bondArray>
    <join atomRefs2="g:nsp2_6_r3 g:h_7_r1" moleculeRefs2="g:nsp2_6 g:h_7" order="S">
      <molecule role="fragment" id="h_7">
        <atomArray>
          <atom elementType="H" x3="1.998" y3="-0.064" z3="-0.0" formalCharge="0" hydrogenCount="0" id="h_7_a1"/>
          <atom title="H" elementType="R" formalCharge="0" hydrogenCount="0" x3="1.6979020929575936" y3="0.15242838582026894" z3="0.0" id="h_7_r1"/>
        </atomArray>
        <bondArray>
          <bond order="S" id="h_7_a1_h_7_r1" atomRefs2="h_7_a1 h_7_r1"/>
        </bondArray>
      </molecule>
    </join>
  </molecule>
  <join atomRefs2="g:nsp2_6_r2 g:carbonyl_8_r1" moleculeRefs2="g:nsp2_6 g:carbonyl_8" order="S">
    <torsion>180</torsion>
  </join>
  <molecule role="fragment" id="carbonyl_8">
    <atomArray>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="6.858584288887507" y3="7.368205459562712" z3="1.672120540673427" id="carbonyl_8_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="7.470354790502688" y3="7.21912165" z3="2.1153032017509776" formalCharge="0" hydrogenCount="0" id="carbonyl_8_c1"/>
      <atom elementType="O" x3="7.621770771606594" y3="6.2131009200000005" z3="2.7265105769419966" formalCharge="0" hydrogenCount="0" id="carbonyl_8_o2"> </atom>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.955168892277741" y3="7.817216360892232" z3="2.1035557116877412" id="carbonyl_8_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
    </atomArray>
    <bondArray>
      <bond order="S" id="carbonyl_8_r1_carbonyl_8_c1" atomRefs2="carbonyl_8_r1 carbonyl_8_c1"/>
      <bond order="D" id="carbonyl_8_c1_carbonyl_8_o2" atomRefs2="carbonyl_8_c1 carbonyl_8_o2"/>
      <bond order="S" id="carbonyl_8_c1_carbonyl_8_r2" atomRefs2="carbonyl_8_c1 carbonyl_8_r2"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:carbonyl_8_r2 g:ch2_9_r1" moleculeRefs2="g:carbonyl_8 g:ch2_9" order="S"/>
  <molecule role="fragment" id="ch2_9">
    <atomArray>
      <atom elementType="R" x3="1.0927029508094934" y3="0.019313350096244575" z3="-0.04489307394726355" id="ch2_9_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="0.703" y3="-0.593" z3="-0.302" id="ch2_9_a2"/>
      <atom elementType="R" x3="-0.00448114334248928" y3="-0.593" z3="0.0019250430859626966" id="ch2_9_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
      <atom elementType="H" x3="0.631" y3="-0.548" z3="-1.389" id="ch2_9_a6"/>
      <atom elementType="H" x3="1.224" y3="-1.505" z3="-0.01" id="ch2_9_a7"/>
    </atomArray>
    <bondArray>
      <bond order="1" id="ch2_9_r1_ch2_9_a2" atomRefs2="ch2_9_r1 ch2_9_a2"/>
      <bond order="1" id="ch2_9_a2_ch2_9_r2" atomRefs2="ch2_9_a2 ch2_9_r2"/>
      <bond order="1" id="ch2_9_a2_ch2_9_a6" atomRefs2="ch2_9_a2 ch2_9_a6"/>
      <bond order="1" id="ch2_9_a2_ch2_9_a7" atomRefs2="ch2_9_a2 ch2_9_a7"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:ch2_9_r2 g:ch2_10_r1" moleculeRefs2="g:ch2_9 g:ch2_10" order="S"/>
  <molecule role="fragment" id="ch2_10">
    <atomArray>
      <atom elementType="R" x3="1.0927029508094934" y3="0.019313350096244575" z3="-0.04489307394726355" id="ch2_10_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="0.703" y3="-0.593" z3="-0.302" id="ch2_10_a2"/>
      <atom elementType="R" x3="-0.00448114334248928" y3="-0.593" z3="0.0019250430859626966" id="ch2_10_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
      <atom elementType="H" x3="0.631" y3="-0.548" z3="-1.389" id="ch2_10_a6"/>
      <atom elementType="H" x3="1.224" y3="-1.505" z3="-0.01" id="ch2_10_a7"/>
    </atomArray>
    <bondArray>
      <bond order="1" id="ch2_10_r1_ch2_10_a2" atomRefs2="ch2_10_r1 ch2_10_a2"/>
      <bond order="1" id="ch2_10_a2_ch2_10_r2" atomRefs2="ch2_10_a2 ch2_10_r2"/>
      <bond order="1" id="ch2_10_a2_ch2_10_a6" atomRefs2="ch2_10_a2 ch2_10_a6"/>
      <bond order="1" id="ch2_10_a2_ch2_10_a7" atomRefs2="ch2_10_a2 ch2_10_a7"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:ch2_10_r2 g:nsp2_11_r1" moleculeRefs2="g:ch2_10 g:nsp2_11" order="S"/>
  <molecule role="fragment" id="nsp2_11">
    <atomArray>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="6.874474431786602" y3="7.364333152820824" z3="1.6836317786234933" id="nsp2_11_r1">
        <label dictRef="cml:torsionEnd">r2</label>
        <label dictRef="cml:torsionEnd">r3</label>
      </atom>
      <atom elementType="N" x3="7.470354790502688" y3="7.21912165" z3="2.1153032017509776" formalCharge="0" hydrogenCount="0" id="nsp2_11_n1"/>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.566039463978429" y3="6.583384494925069" z3="2.5015449821412834" id="nsp2_11_r3"> </atom>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.942576318205662" y3="7.801681433336589" z3="2.103860841299773" id="nsp2_11_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
    </atomArray>
    <bondArray>
      <bond order="S" id="nsp2_11_r1_nsp2_11_n1" atomRefs2="nsp2_11_r1 nsp2_11_n1"/>
      <bond order="S" id="nsp2_11_n1_nsp2_11_r2" atomRefs2="nsp2_11_n1 nsp2_11_r2"/>
      <bond order="S" id="nsp2_11_n1_nsp2_11_r3" atomRefs2="nsp2_11_n1 nsp2_11_r3"/>
    </bondArray>
    <join atomRefs2="g:nsp2_11_r3 g:h_12_r1" moleculeRefs2="g:nsp2_11 g:h_12" order="S">
      <molecule role="fragment" id="h_12">
        <atomArray>
          <atom elementType="H" x3="1.998" y3="-0.064" z3="-0.0" formalCharge="0" hydrogenCount="0" id="h_12_a1"/>
          <atom title="H" elementType="R" formalCharge="0" hydrogenCount="0" x3="1.6979020929575936" y3="0.15242838582026894" z3="0.0" id="h_12_r1"/>
        </atomArray>
        <bondArray>
          <bond order="S" id="h_12_a1_h_12_r1" atomRefs2="h_12_a1 h_12_r1"/>
        </bondArray>
      </molecule>
    </join>
  </molecule>
  <join atomRefs2="g:nsp2_11_r2 g:carbonyl_13_r1" moleculeRefs2="g:nsp2_11 g:carbonyl_13" order="S">
    <torsion>180</torsion>
  </join>
  <molecule role="fragment" id="carbonyl_13">
    <atomArray>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="6.858584288887507" y3="7.368205459562712" z3="1.672120540673427" id="carbonyl_13_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="7.470354790502688" y3="7.21912165" z3="2.1153032017509776" formalCharge="0" hydrogenCount="0" id="carbonyl_13_c1"/>
      <atom elementType="O" x3="7.621770771606594" y3="6.2131009200000005" z3="2.7265105769419966" formalCharge="0" hydrogenCount="0" id="carbonyl_13_o2"> </atom>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.955168892277741" y3="7.817216360892232" z3="2.1035557116877412" id="carbonyl_13_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
    </atomArray>
    <bondArray>
      <bond order="S" id="carbonyl_13_r1_carbonyl_13_c1" atomRefs2="carbonyl_13_r1 carbonyl_13_c1"/>
      <bond order="D" id="carbonyl_13_c1_carbonyl_13_o2" atomRefs2="carbonyl_13_c1 carbonyl_13_o2"/>
      <bond order="S" id="carbonyl_13_c1_carbonyl_13_r2" atomRefs2="carbonyl_13_c1 carbonyl_13_r2"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:carbonyl_13_r2 g:ch2_14_r1" moleculeRefs2="g:carbonyl_13 g:ch2_14" order="S"/>
  <molecule role="fragment" id="ch2_14">
    <atomArray>
      <atom elementType="R" x3="1.0927029508094934" y3="0.019313350096244575" z3="-0.04489307394726355" id="ch2_14_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="0.703" y3="-0.593" z3="-0.302" id="ch2_14_a2"/>
      <atom elementType="R" x3="-0.00448114334248928" y3="-0.593" z3="0.0019250430859626966" id="ch2_14_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
      <atom elementType="H" x3="0.631" y3="-0.548" z3="-1.389" id="ch2_14_a6"/>
      <atom elementType="H" x3="1.224" y3="-1.505" z3="-0.01" id="ch2_14_a7"/>
    </atomArray>
    <bondArray>
      <bond order="1" id="ch2_14_r1_ch2_14_a2" atomRefs2="ch2_14_r1 ch2_14_a2"/>
      <bond order="1" id="ch2_14_a2_ch2_14_r2" atomRefs2="ch2_14_a2 ch2_14_r2"/>
      <bond order="1" id="ch2_14_a2_ch2_14_a6" atomRefs2="ch2_14_a2 ch2_14_a6"/>
      <bond order="1" id="ch2_14_a2_ch2_14_a7" atomRefs2="ch2_14_a2 ch2_14_a7"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:ch2_14_r2 g:ch2_15_r1" moleculeRefs2="g:ch2_14 g:ch2_15" order="S"/>
  <molecule role="fragment" id="ch2_15">
    <atomArray>
      <atom elementType="R" x3="1.0927029508094934" y3="0.019313350096244575" z3="-0.04489307394726355" id="ch2_15_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="0.703" y3="-0.593" z3="-0.302" id="ch2_15_a2"/>
      <atom elementType="R" x3="-0.00448114334248928" y3="-0.593" z3="0.0019250430859626966" id="ch2_15_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
      <atom elementType="H" x3="0.631" y3="-0.548" z3="-1.389" id="ch2_15_a6"/>
      <atom elementType="H" x3="1.224" y3="-1.505" z3="-0.01" id="ch2_15_a7"/>
    </atomArray>
    <bondArray>
      <bond order="1" id="ch2_15_r1_ch2_15_a2" atomRefs2="ch2_15_r1 ch2_15_a2"/>
      <bond order="1" id="ch2_15_a2_ch2_15_r2" atomRefs2="ch2_15_a2 ch2_15_r2"/>
      <bond order="1" id="ch2_15_a2_ch2_15_a6" atomRefs2="ch2_15_a2 ch2_15_a6"/>
      <bond order="1" id="ch2_15_a2_ch2_15_a7" atomRefs2="ch2_15_a2 ch2_15_a7"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:ch2_15_r2 g:nsp2_16_r1" moleculeRefs2="g:ch2_15 g:nsp2_16" order="S"/>
  <molecule role="fragment" id="nsp2_16">
    <atomArray>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="6.874474431786602" y3="7.364333152820824" z3="1.6836317786234933" id="nsp2_16_r1">
        <label dictRef="cml:torsionEnd">r2</label>
        <label dictRef="cml:torsionEnd">r3</label>
      </atom>
      <atom elementType="N" x3="7.470354790502688" y3="7.21912165" z3="2.1153032017509776" formalCharge="0" hydrogenCount="0" id="nsp2_16_n1"/>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.566039463978429" y3="6.583384494925069" z3="2.5015449821412834" id="nsp2_16_r3"> </atom>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.942576318205662" y3="7.801681433336589" z3="2.103860841299773" id="nsp2_16_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
    </atomArray>
    <bondArray>
      <bond order="S" id="nsp2_16_r1_nsp2_16_n1" atomRefs2="nsp2_16_r1 nsp2_16_n1"/>
      <bond order="S" id="nsp2_16_n1_nsp2_16_r2" atomRefs2="nsp2_16_n1 nsp2_16_r2"/>
      <bond order="S" id="nsp2_16_n1_nsp2_16_r3" atomRefs2="nsp2_16_n1 nsp2_16_r3"/>
    </bondArray>
    <join atomRefs2="g:nsp2_16_r3 g:h_17_r1" moleculeRefs2="g:nsp2_16 g:h_17" order="S">
      <molecule role="fragment" id="h_17">
        <atomArray>
          <atom elementType="H" x3="1.998" y3="-0.064" z3="-0.0" formalCharge="0" hydrogenCount="0" id="h_17_a1"/>
          <atom title="H" elementType="R" formalCharge="0" hydrogenCount="0" x3="1.6979020929575936" y3="0.15242838582026894" z3="0.0" id="h_17_r1"/>
        </atomArray>
        <bondArray>
          <bond order="S" id="h_17_a1_h_17_r1" atomRefs2="h_17_a1 h_17_r1"/>
        </bondArray>
      </molecule>
    </join>
  </molecule>
  <join atomRefs2="g:nsp2_16_r2 g:carbonyl_18_r1" moleculeRefs2="g:nsp2_16 g:carbonyl_18" order="S">
    <torsion>180</torsion>
  </join>
  <molecule role="fragment" id="carbonyl_18">
    <atomArray>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="6.858584288887507" y3="7.368205459562712" z3="1.672120540673427" id="carbonyl_18_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="7.470354790502688" y3="7.21912165" z3="2.1153032017509776" formalCharge="0" hydrogenCount="0" id="carbonyl_18_c1"/>
      <atom elementType="O" x3="7.621770771606594" y3="6.2131009200000005" z3="2.7265105769419966" formalCharge="0" hydrogenCount="0" id="carbonyl_18_o2"> </atom>
      <atom elementType="R" formalCharge="0" hydrogenCount="0" x3="7.955168892277741" y3="7.817216360892232" z3="2.1035557116877412" id="carbonyl_18_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
    </atomArray>
    <bondArray>
      <bond order="S" id="carbonyl_18_r1_carbonyl_18_c1" atomRefs2="carbonyl_18_r1 carbonyl_18_c1"/>
      <bond order="D" id="carbonyl_18_c1_carbonyl_18_o2" atomRefs2="carbonyl_18_c1 carbonyl_18_o2"/>
      <bond order="S" id="carbonyl_18_c1_carbonyl_18_r2" atomRefs2="carbonyl_18_c1 carbonyl_18_r2"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:carbonyl_18_r2 g:ch2_19_r1" moleculeRefs2="g:carbonyl_18 g:ch2_19" order="S"/>
  <molecule role="fragment" id="ch2_19">
    <atomArray>
      <atom elementType="R" x3="1.0927029508094934" y3="0.019313350096244575" z3="-0.04489307394726355" id="ch2_19_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="0.703" y3="-0.593" z3="-0.302" id="ch2_19_a2"/>
      <atom elementType="R" x3="-0.00448114334248928" y3="-0.593" z3="0.0019250430859626966" id="ch2_19_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
      <atom elementType="H" x3="0.631" y3="-0.548" z3="-1.389" id="ch2_19_a6"/>
      <atom elementType="H" x3="1.224" y3="-1.505" z3="-0.01" id="ch2_19_a7"/>
    </atomArray>
    <bondArray>
      <bond order="1" id="ch2_19_r1_ch2_19_a2" atomRefs2="ch2_19_r1 ch2_19_a2"/>
      <bond order="1" id="ch2_19_a2_ch2_19_r2" atomRefs2="ch2_19_a2 ch2_19_r2"/>
      <bond order="1" id="ch2_19_a2_ch2_19_a6" atomRefs2="ch2_19_a2 ch2_19_a6"/>
      <bond order="1" id="ch2_19_a2_ch2_19_a7" atomRefs2="ch2_19_a2 ch2_19_a7"/>
    </bondArray>
  </molecule>
  <join atomRefs2="g:ch2_19_r2 g:ch2_20_r1" moleculeRefs2="g:ch2_19 g:ch2_20" order="S"/>
  <molecule role="fragment" id="ch2_20">
    <atomArray>
      <atom elementType="R" x3="1.0927029508094934" y3="0.019313350096244575" z3="-0.04489307394726355" id="ch2_20_r1">
        <label dictRef="cml:torsionEnd">r2</label>
      </atom>
      <atom elementType="C" x3="0.703" y3="-0.593" z3="-0.302" id="ch2_20_a2"/>
      <atom elementType="R" x3="-0.00448114334248928" y3="-0.593" z3="0.0019250430859626966" id="ch2_20_r2">
        <label dictRef="cml:torsionEnd">r1</label>
      </atom>
      <atom elementType="H" x3="0.631" y3="-0.548" z3="-1.389" id="ch2_20_a6"/>
      <atom elementType="H" x3="1.224" y3="-1.505" z3="-0.01" id="ch2_20_a7"/>
    </atomArray>
    <bondArray>
      <bond order="1" id="ch2_20_r1_ch2_20_a2" atomRefs2="ch2_20_r1 ch2_20_a2"/>
      <bond order="1" id="ch2_20_a2_ch2_20_r2" atomRefs2="ch2_20_a2 ch2_20_r2"/>
      <bond order="1" id="ch2_20_a2_ch2_20_a6" atomRefs2="ch2_20_a2 ch2_20_a6"/>
      <bond order="1" id="ch2_20_a2_ch2_20_a7" atomRefs2="ch2_20_a2 ch2_20_a7"/>
    </bondArray>
  </molecule>
</fragment>
