\documentclass{report}
\usepackage{hyperref}
% WARNING: THIS SHOULD BE MODIFIED DEPENDING ON THE LETTER/A4 SIZE
\oddsidemargin 0cm
\evensidemargin 0cm
\marginparsep 0cm
\marginparwidth 0cm
\parindent 0cm
\sloppy
\hyphenation{anotherverylong-wordthistimeitshouldbebrokenbecauseofhyphenation}
\setlength{\textwidth}{\paperwidth}
\addtolength{\textwidth}{-2in}


% Conditional define to determine if pdf output is used
\newif\ifpdf
\ifx\pdfoutput\undefined
\pdffalse
\else
\pdfoutput=1
\pdftrue
\fi

\ifpdf
  \usepackage[pdftex]{graphicx}
\else
  \usepackage[dvips]{graphicx}
\fi

% Write Document information for pdflatex/pdftex
\ifpdf
\pdfinfo{
 /Author     (Pasdoc)
 /Title      ()
}
\fi


% definitons for warning and note tag
\usepackage[most]{tcolorbox}
\newtcolorbox{tcbwarning}{
 breakable,
 enhanced jigsaw,
 top=0pt,
 bottom=0pt,
 titlerule=0pt,
 bottomtitle=0pt,
 rightrule=0pt,
 toprule=0pt,
 bottomrule=0pt,
 colback=white,
 arc=0pt,
 outer arc=0pt,
 title style={white},
 fonttitle=\color{black}\bfseries,
 left=8pt,
 colframe=red,
 title={Warning:},
}
\newtcolorbox{tcbnote}{
 breakable,
 enhanced jigsaw,
 top=0pt,
 bottom=0pt,
 titlerule=0pt,
 bottomtitle=0pt,
 rightrule=0pt,
 toprule=0pt,
 bottomrule=0pt,
 colback=white,
 arc=0pt,
 outer arc=0pt,
 title style={white},
 fonttitle=\color{black}\bfseries,
 left=8pt,
 colframe=yellow,
 title={Note:},
}

\begin{document}
\label{toc}\tableofcontents
\newpage
% special variable used for calculating some widths.
\newlength{\tmplength}
\chapter{Unit ok{\_}latex{\_}head}
\label{ok_latex_head}
\index{ok{\_}latex{\_}head}
\section{Description}
Unit testing --latex{-}head option. Very long word: unitfortestingoflatexheadoptionveryveryveryveryverylongword.

Another very long word, this time it should be broken because of {\textbackslash}hyphenation: anotherverylongwordthistimeitshouldbebrokenbecauseofhyphenation.
\end{document}
